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Elements, Compounds, Mixtures and Separation

Is Matter Pure: Elements, Compounds, Mixtures and Separation

Elements, Compounds, Mixtures and Separation

Is Matter Pure?

What you'll learn

  • The difference between pure substances and mixtures.
  • What elements and compounds are.
  • Types of mixtures: homogeneous (solutions) and heterogeneous.
  • Colloidal solutions — what they are and how to identify them.
  • Methods to separate different types of mixtures.

Key concepts

Pure substances vs mixtures

Pure substanceMixture
CompositionFixed (constant)Variable
PropertiesFixed melting/boiling pointNo sharp melting/boiling point
SeparationCannot be separated by physical methodsCan be separated by physical methods
ExamplesGold, water, salt, O₂Salt water, air, alloys, soil

Elements

  • Element: a pure substance made of only one type of atom; cannot be broken down further by chemical means.
  • 118 elements known; 94 occur naturally.
  • Classified as metals (Na, Fe, Cu, Au), non-metals (C, O, N, S, Cl), metalloids (Si, As, B).
PropertyMetalsNon-metals
State (mostly)SolidSolid/gas/liquid
LustreShinyDull
ConductivityGood conductorPoor conductor (except graphite)
MalleabilityMalleableBrittle (if solid)
ExampleIron, copperSulfur, nitrogen
  • Noble gases (He, Ne, Ar, Kr, Xe, Rn): non-metals; inert (do not react under normal conditions).

Compounds

  • Compound: a pure substance formed when two or more elements combine chemically in a fixed ratio.
  • Properties are entirely different from constituent elements.
  • Can only be separated by chemical methods (not physical).

Examples:

CompoundElementsFormulaProperties differ from elements?
WaterH + OH₂OYes — liquid, not flammable; H is explosive gas, O supports burning
Common saltNa + ClNaClYes — edible solid; Na is reactive metal, Cl₂ is toxic gas
AmmoniaN + HNH₃Yes — pungent gas used in fertilisers
Carbon dioxideC + OCO₂Yes — gas that extinguishes fire; C burns, O supports burning
  • Law of Definite Proportions (Proust): a compound always contains the same elements in the same mass ratio (e.g., H₂O always has H:O = 1:8 by mass).

Mixtures

  • Mixture: two or more substances combined without chemical reaction, in any proportion.
  • Constituents retain their original properties.
  • Separated by physical methods.

Types of mixtures

1. Homogeneous mixture (Solution)

  • Uniform composition throughout; constituents not visually distinguishable.
  • Examples: saltwater, lemonade, air, alloys (brass = Cu + Zn), alcohol + water.
  • Components: solute (dissolved) + solvent (dissolving medium).
  • Concentration = amount of solute per unit volume/mass of solution.
  • Saturated solution: maximum solute dissolved at a given temperature.

2. Heterogeneous mixture

  • Non-uniform composition; constituents visually distinguishable or settles on standing.
  • Examples: soil, sand in water, oil in water, smoke, granite.
  • Sub-types:
    • Suspension: large particles (> 1000 nm), settle on standing, opaque. Example: muddy water, chalk in water.
    • Colloid: medium particles (1–1000 nm), do not settle, scatter light. Example: milk, fog, smoke, blood, jelly.

Colloidal solutions (Colloids)

  • Particles between 1 nm and 1000 nm — too small to see but large enough to scatter light.
  • Tyndall effect: scattering of light by colloidal particles — visible as a beam of light through the colloid.
    • Sky is blue because of Tyndall scattering of sunlight by air particles.
    • Headlights visible in fog = Tyndall effect.
    • Milk appears white = Tyndall scattering of fat droplets.
PropertyTrue solutionColloidSuspension
Particle size< 1 nm1–1000 nm> 1000 nm
AppearanceTransparentTranslucentOpaque
Tyndall effectNoYesNo (just blocks light)
SettlingNoNoYes (on standing)
FiltrationPasses filter paperPasses filter paperDoes NOT pass filter paper
ExampleSalt waterMilk, fogMuddy water

Dispersed phase = substance spread out; Dispersion medium = substance in which it is spread.

Colloid typeDispersed phaseDispersion mediumExample
AerosolLiquidGasFog, mist, clouds
AerosolSolidGasSmoke, dust storm
FoamGasLiquidShaving cream, whipped cream
EmulsionLiquidLiquidMilk, mayonnaise
SolSolidLiquidBlood, ink, paint
GelLiquidSolidCheese, jelly, butter
Solid foamGasSolidPumice stone, styrofoam

Separation of mixtures

Mixture typeMethodPrinciple
Insoluble solid + liquidFiltrationParticle size
Soluble solid + liquidEvaporation / CrystallisationSolubility difference
Two miscible liquids (different b.p.)Fractional distillationBoiling point difference
Two immiscible liquidsSeparating funnelDensity difference
Dyes in inkChromatographyDifferent speeds on paper
Two dissolved solids (different solubility)CrystallisationSolubility vs temperature
Mixture of gasesFractional distillationLiquefaction then boiling point
  • Chromatography: separates coloured components (dyes, chlorophyll) — components travel at different rates on paper; used in forensics, food testing, drug detection.
  • Fractional distillation of air: liquefies air → warm up → N₂ boils first (−196°C), then O₂ (−183°C), then Ar.

Elements, compounds and mixtures — summary

MATTER
├── Pure substances
│   ├── Elements (one type of atom)
│   └── Compounds (two+ elements, fixed ratio, chemical bond)
└── Mixtures
    ├── Homogeneous (solutions, alloys)
    └── Heterogeneous
        ├── Colloids (Tyndall effect)
        └── Suspensions (settle on standing)

Quick check

  • What is the difference between a compound and a mixture?
  • Name the law that governs the composition of compounds.
  • What is the Tyndall effect? Give two examples from daily life.
  • How would you separate: (a) oil and water (b) two miscible liquids (c) dyes in ink?
  • Classify: milk, air, saltwater, soil, blood — as solution, colloid, or suspension.

Open the Practice tab for graded questions on Is Matter Pure.

Key Takeaways (TL;DR)

  • What you'll learn
  • Key concepts
  • Quick check

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