States of Matter, Interconversion and Evaporation
Matter in Our Surroundings: States of Matter, Interconversion and Evaporation
States of Matter, Interconversion and Evaporation
Matter in Our Surroundings
What you'll learn
- What matter is; its physical states.
- Properties of solids, liquids and gases at the particle level.
- How matter changes state — melting, boiling, sublimation, condensation.
- Evaporation and why it causes cooling.
- Key terms: latent heat, boiling point, melting point.
Key concepts
What is matter?
- Matter: anything that has mass and occupies space (volume).
- Made up of tiny particles (atoms and molecules) that are always in motion.
- Particles have spaces between them and forces of attraction between them.
- Three classical states: solid, liquid, gas.
- Fourth state: plasma (inside stars, lightning) — not covered at this level.
Particle theory of matter
| Property | Solid | Liquid | Gas |
|---|---|---|---|
| Arrangement | Regular, closely packed | Random, moderately close | Random, far apart |
| Intermolecular forces | Very strong | Moderate | Very weak |
| Movement of particles | Vibrate in fixed positions | Slide past each other | Move freely at high speed |
| Shape | Fixed | Takes shape of container | Fills entire container |
| Volume | Fixed | Fixed | No fixed volume |
| Compressibility | Almost none | Very little | High |
| Density | High | Moderate | Very low |
| Diffusion | Very slow | Slow | Fast |
Properties of each state in detail
Solids
- Rigid: cannot be compressed or changed in shape easily.
- High density: particles packed closely.
- Some solids can be moulded under high pressure (e.g., ice, wax).
- Crystal structure: particles in a regular geometric arrangement (salt, diamond).
- Amorphous solids: no regular arrangement (glass, rubber, plastic) — sometimes called pseudo-liquids.
Liquids
- Fluidity: can flow; takes shape of container.
- Surface tension: liquid surface behaves like a stretched membrane (water strider insects walk on water).
- Viscosity: resistance to flow (honey > water > alcohol).
- No fixed shape but fixed volume.
Gases
- Fill entire container: particles move randomly and hit all walls.
- Highly compressible: large spaces between particles (LPG in cylinder compressed to liquid).
- Low density.
- Pressure: particles constantly hitting container walls = gas pressure.
- Diffusion: gases spread quickly (smell of food, perfume).
Interconversion of states
Matter can change from one state to another by adding or removing heat energy:
SOLID ←→ LIQUID ←→ GAS
| Change | Process | Energy change |
|---|---|---|
| Solid → Liquid | Melting (Fusion) | Heat energy absorbed |
| Liquid → Solid | Freezing (Solidification) | Heat energy released |
| Liquid → Gas | Vaporisation (Boiling) | Heat energy absorbed |
| Gas → Liquid | Condensation (Liquefaction) | Heat energy released |
| Solid → Gas directly | Sublimation | Heat energy absorbed |
| Gas → Solid directly | Deposition | Heat energy released |
Examples of sublimation:
- Dry ice (solid CO₂) → CO₂ gas (used in fog machines, cold storage).
- Iodine (purple solid) → purple vapour on heating.
- Camphor (naphthalene balls) → vapour.
- Ammonium chloride sublimes and is used to separate it from other salts.
Melting point and Boiling point
- Melting point: temperature at which a solid converts to liquid at standard pressure.
- Ice: 0°C = 273 K.
- Pure substances have a sharp melting point — used to check purity.
- Boiling point: temperature at which liquid converts to gas throughout its volume.
- Water: 100°C = 373 K at 1 atm pressure.
- Effect of pressure:
- Increased pressure → raises boiling point (pressure cooker: water boils at ~120°C → food cooks faster).
- Decreased pressure → lowers boiling point (on mountains, water boils at < 100°C → food takes longer to cook).
Latent heat
- When a substance is changing state, temperature does not change even though heat is being added/removed.
- This heat is used to break/form intermolecular bonds, not raise temperature.
- Latent heat of fusion: heat absorbed to melt 1 kg of solid → liquid at melting point.
- Ice: 336,000 J/kg (336 kJ/kg).
- Latent heat of vaporisation: heat absorbed to vaporise 1 kg of liquid → gas at boiling point.
- Water: 2,260,000 J/kg (2,260 kJ/kg) — very high → why steam burns are worse than boiling water burns.
Evaporation
- Evaporation: liquid changing to vapour at temperatures below the boiling point.
- Occurs only at the surface (unlike boiling which occurs throughout).
- Faster-moving surface particles escape into air.
Factors affecting evaporation rate
| Factor | Effect |
|---|---|
| Temperature | Higher temp → more particles have enough energy → faster evaporation |
| Surface area | Larger surface → more particles exposed → faster |
| Humidity | High humidity → air already has moisture → slows evaporation |
| Wind speed | Wind removes vapour from surface → keeps concentration gradient high → faster |
Evaporation causes cooling
- Particles that escape are the fastest-moving (highest kinetic energy) ones.
- Average kinetic energy of remaining liquid decreases → temperature falls.
- Examples:
- Sweating cools the body (sweat evaporates → takes heat from skin).
- Earthen pots (matka) keep water cool (water seeps through tiny pores, evaporates → cools remaining water).
- Acetone/spirit on skin feels cold (evaporates quickly).
- Desert coolers work by evaporation.
Kelvin scale
- SI unit of temperature: Kelvin (K).
- K = °C + 273
- Absolute zero = 0 K = −273°C (theoretically lowest possible temperature; all particle motion stops).
- Water freezes: 273 K; Water boils: 373 K.
Plasma — the fourth state
- At extremely high temperatures (thousands to millions of °C), atoms lose electrons → mixture of free electrons and ions.
- Plasma: ionised gas; most common state of matter in the universe (stars are plasma).
- Examples on Earth: lightning, neon signs, fluorescent tube lights, plasma TV screens.
Quick check
- Compare solids, liquids and gases on: arrangement, movement, compressibility.
- What is sublimation? Give two examples.
- What is latent heat of vaporisation? Why do steam burns hurt more than boiling water burns?
- List four factors that increase the rate of evaporation.
- Why does an earthen pot keep water cool? Explain using evaporation.
Open the Practice tab for graded questions on Matter in Our Surroundings.
Key Takeaways (TL;DR)
- What you'll learn
- Key concepts
- Quick check
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