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Sublimation

Sublimation and Thermal Effects: Sublimation

Sublimation

Sublimation

What you'll learn

  • Most solids melt into a liquid before turning into gas. But some solids can turn directly into gas, without ever becoming liquid. This is called sublimation.
  • Common examples: camphor (kapur), naphthalene balls (mothballs), dry ice (solid carbon dioxide), iodine crystals, and some solid air-freshener blocks.
  • The reverse process — a gas changing directly into a solid — is called deposition. Frost forming on a very cold window from water vapour in the air is an everyday example of deposition.

Key concepts

Level 1 — What is sublimation?

Verbal: Sublimation is the change of state where a solid turns directly into a gas, skipping the liquid state completely.

Symbolic: Solid → Gas (directly, no liquid stage).

SubstanceWhat you observeChange of state
Camphor (kapur)Slowly disappears, no liquid left behindSublimation
Naphthalene ballsShrink away in a wardrobe over weeksSublimation
Dry iceTurns into cold fog/gas, no wet puddleSublimation
Iodine crystals (heated)Give off violet vapour directlySublimation

Level 2 — Sublimation vs melting/evaporation

Verbal: Melting and evaporation both pass through a liquid stage (solid → liquid → gas). Sublimation skips the liquid stage entirely (solid → gas directly).

Real-life: Ice melts into water first, then the water evaporates — that is NOT sublimation. But camphor never becomes a liquid puddle — that IS sublimation.

Worked example

A camphor tablet placed in an open dish becomes smaller and smaller over a few days, with no liquid puddle ever forming. What change of state is happening?

Step 1 — Camphor starts as a solid.
Step 2 — It never becomes a liquid; no puddle appears.
Step 3 — It slowly turns into gas (vapour) that spreads into the air.
Answer: This is sublimation — solid directly to gas.

Common mistakes

MistakeWhy it happensFix
Thinking camphor "evaporates" like waterConfusing with liquid evaporationCamphor never becomes liquid, so it sublimes, not evaporates
Thinking sublimation only happens to iceOvergeneralisingIce normally melts first; camphor, naphthalene, and dry ice are true subliming solids
Forgetting the reverse process has its own nameNot linking related termsGas to solid directly is called deposition

Quick check

  • Name two substances that sublime.
  • What is the reverse of sublimation called?
  • How is sublimation different from evaporation?

Stretch: Why is dry ice useful for transporting ice cream compared to ordinary ice?

Revision tip: Remember: sublimation always skips the liquid stage — solid straight to gas.

Open the Practice tab for graded questions on Sublimation.

Key Takeaways (TL;DR)

  • What you'll learn
  • Key concepts
  • Worked example
  • Common mistakes

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