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Interconversion

Melting, boiling, sublimation; latent heat.

Interconversion

Interconversion of States

What you'll learn

  • Melting (fusion) — solid → liquid; freezing — liquid → solid.
  • Evaporation/vaporisation — liquid → gas; condensation — gas → liquid.
  • Sublimation — solid → gas directly (camphor, naphthalene, dry ice).
  • Role of temperature and pressure; latent heat concept (introductory).

Key concepts

  1. Melting point — temperature at which solid melts (ice: 0 °C at 1 atm).
  2. Boiling point — liquid boils (water: 100 °C at 1 atm).
  3. Latent heat of fusion — heat for melting without temperature rise.
  4. Latent heat of vaporisation — heat for boiling/evaporation at constant T.
  5. Pressure effect — higher pressure raises boiling point (pressure cooker).
  6. Diagram (text) — heating curve: plateaus at melting and boiling points.
  7. NCERT Ch. 1 — dry ice sublimes; wax melts on heating.
  8. Real world — refrigeration cycle; snow sublimes in cold dry weather.

Worked example

Why does temperature stay at 100 °C while water boils?

Step 1 — Heat supplied breaks intermolecular bonds (phase change).
Step 2 — Energy used as **latent heat of vaporisation**, not to raise temperature.
Step 3 — Thermometer stays at 100 °C until all liquid vaporised (in open container).
Step 4 — After boiling completes, temperature of steam can rise above 100 °C.
Conclusion: phase change absorbs heat at constant temperature.

Common mistakes

  • Thinking boiling and evaporation are identical (boiling at fixed T throughout liquid; evaporation at surface any T).
  • Misconception: cold objects cannot sublime (sublimation depends on substance, not only heat).
  • Confusing condensation with freezing.
  • Forgetting deposition (gas → solid directly).
  • Assuming melting always needs high temperature (ice melts at 0 °C).

Quick check

  • Define melting point and boiling point.
  • What is sublimation? Give two examples.
  • Why does a pressure cooker cook food faster?
  • What is latent heat?

Open the Practice tab for graded questions on Interconversion of States.

Key Takeaways (TL;DR)

  • What you'll learn
  • Key concepts
  • Worked example
  • Common mistakes

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